SURFACE MECHANISM OF HYDROGEN OXIDATION OVER RHODIUM
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****                                                                  *
****     H2/O2 OVER RH - SURFASE MECHANISM                            *
****     thermodynamically constant (273 - 1273K)                     *
****                                                                  *
****     C. Karakaya, O. Deutschmann                                  *
****     KIT (Karlsruhe Institute of Technology)                      *
****                                                                  *
****                                                                  *
****     References:                                                  *
****     C. Karakaya, O. Deutschmann, Chemical Engineering Science,   * 
****     89 (2012) 171-184                                            * 
****     www.detchem.com/mechanisms                                   * 
****     KIT (Karlsruhe Institute of Technology)                      *
****     Contact: mail@detchem.com (O. Deutschmann)                   * 
****     www.detchem.com/mechanisms                                   * 
****                                                                  *
****                                                                  *
****     Kinetic data:                                                *
****      k = A * T**b * exp (-Ea/RT)         A          b       Ea   *
****                                       (cm,mol,s)    -     kJ/mol *
****                                                                  *
****     STICK: A in next reaction is initial sticking coefficient    *
****                                                                  *
****                                                                  *
****     (DETCHEM format)                                             *
****                                                                  * 
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**** 1.  ADSORPTION                   
STICK
H2      +Rh(s)   +Rh(s)   >H(s)    +H(s)           0.03      0         0
STICK
O2      +Rh(s)   +Rh(s)   >O(s)    +O(s)           0.01      0         0
STICK
H2O     +Rh(s)   >H2O(s)                            0.1      0         0
H(s)    +H(s)    >Rh(s)   +Rh(s)   +H2        5.574E+19  0.239    59.691
O(s)    +O(s)    >Rh(s)   +Rh(s)   +O2        5.329E+22 -0.137   386.995
H2O(s)  >H2O     +Rh(s)                       6.858E+14 -0.280    44.993
H(s)    +O(s)    >OH(s)   +Rh(s)              8.826E+21 -0.048    73.365
OH(s)   +Rh(s)   >H(s)    +O(s)               1.000E+21  0.045    48.041
OH(s)   +H(s)    >H2O(s)  +Rh(s)              1.743E+22 -0.127    41.731
H2O(s)  +Rh(s)   >H(s)    +OH(s)              5.408E+22  0.129    98.220
OH(s)   +OH(s)   >H2O(s)  +O(s)               5.736E+20 -0.081   121.594
H2O(s)  +O(s)    >OH(s)   +OH(s)              1.570E+22  0.081   203.407
END