SURFACE MECHANISM OF CO OXIDATION OVER RHODIUM
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****                                                                  *
****     CO/O2 OVER RH - SURFASE MECHANISM                            *
****     thermodynamically constant (273 - 1273K)                     *
****                                                                  *
****     C. Karakaya, O. Deutschmann 2013                             *
****     KIT (Karlsruhe Institute of Technology)                      *
****                                                                  *
****     References:                                                  *
****     H. Karadeniz, C. Karakaya, S. Tischer, O. Deutschmann,       *
****     Chemical Engineering Science, Submitted (2013).              *
****     www.detchem.com/mechanisms                                   * 
****     KIT (Karlsruhe Institute of Technology)                      *
****     Contact: mail@detchem.com (O. Deutschmann)                   * 
****     www.detchem.com/mechanisms                                   * 
****                                                                  *
****                                                                  *
****     Kinetic data:                                                *
****      k = A * T**b * exp (-Ea/RT)         A          b       Ea   *
****                                       (cm,mol,s)    -     kJ/mol *
****                                                                  *
****     STICK: A in next reaction is initial sticking coefficient    *
****                                                                  *
****                                                                  *
****     (DETCHEM format)                                             *
****                                                                  * 
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**** 1.  ADSORPTION                   
STICK
O2      +Rh(s)   +Rh(s)   >O(s)    +O(s)           0.01      0         0
STICK
CO2     +Rh(s)   >CO2(s)                          0.048      0         0
STICK
CO      +Rh(s)   >CO(s)                          0.4971      0         0
O(s)    +O(s)    >Rh(s)   +Rh(s)   +O2        5.329E+22 -0.137   386.995
CO(s)   >CO      +Rh(s)                       1.300E+13  0.295   134.070
$CO(s)                                                       0        47
CO2(s)  >CO2     +Rh(s)                       3.920E+11  0.315    20.505
C(s)    +O(s)    >CO(s)   +Rh(s)              1.173E+22  0.000    92.142
CO(s)   +Rh(s)   >C(s)    +O(s)               6.390E+21 -0.000   174.758
$CO(s)                                                       0        47
CO(s)   +O(s)    >CO2(s)  +Rh(s)              6.183E+21  0.034   129.982
$CO(s)                                                       0        47
CO2(s)  +Rh(s)   >CO(s)   +O(s)               5.752E+22 -0.175   106.492
END