SURFACE MECHANISM FOR OXIDATION OF CO OVER PLATINUM
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****                                                                  *
****     CO/O2 OVER PT - SURFACE MECHANISM                            *
****     thermodynamically consistent (273 - 1273K)                   *
****                                                                  *
****     D. CHAN, O. DEUTSCHMANN                                      *
****     KIT (Karlsruhe Institute of Technology)                      *
****                                                                  *
****     References:                                                  *
****     D. Chan, S. Tischer, J. Heck, C. Diehm, O. Deutschmann       *
****     Applied Catalysis B: Environmental 156–157 (2014) 153–165    *
****     www.detchem.com/mechanisms                                   * 
****     KIT (Karlsruhe Institute of Technology)                      *
****     Contact: mail@detchem.com (O. Deutschmann)                   * 
****     www.detchem.com/mechanisms                                   * 
****                                                                  *
****                                                                  *
****     Kinetic data:                                                *
****      k = A * T**b * exp (-Ea/RT)         A          b       Ea   *
****                                       (cm,mol,s)    -     kJ/mol *
****                                                                  *
****     STICK: A in next reaction is initial sticking coefficient    *
****                                                                  *
****                                                                  *
****     (DETCHEM format)                                             *
****                                                                  * 
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SURFACE MECHANISM
STICK
(Pt)    +O2      >O2(Pt)                      5.000E-02  0.000     0.000
O2(Pt)  >(Pt)    +O2                          5.243E+11 -0.069    19.572
(Pt)    +O2(Pt)  >O(Pt)   +O(Pt)              8.325E+13 -0.000    39.933
O(Pt)   +O(Pt)   >(Pt)    +O2(Pt)             4.444E+21  0.000   264.067
$O(Pt)                                                   0.000    88.200
STICK
(Pt)    +CO      >CO(Pt)                      8.400E-01  0.000     0.000
CO(Pt)  >(Pt)    +CO                          7.635E+12 -0.139   143.145
$CO(Pt)                                                  0.000    29.300
STICK
(Pt)    +CO2     >CO2(Pt)                     3.193E-03 -0.035     2.686
CO2(Pt) >(Pt)    +CO2                         1.894E+10  0.139    21.854
CO(Pt)  +O2(Pt)  >O(Pt)   +CO2(Pt)            4.124E+13  0.069     9.494
$O(Pt)                                                   0.000   -44.100
O(Pt)   +CO2(Pt) >CO(Pt)  +O2(Pt)             2.910E+23 -0.069   272.505
$CO(Pt)                                                  0.000   -29.300
CO(Pt)  +O(Pt)   >(Pt)    +CO2(Pt)            4.764E+13  0.069   101.361
$CO(Pt)                                                  0.000    29.300
(Pt)    +CO2(Pt) >CO(Pt)  +O(Pt)              6.297E+20 -0.069   140.239
$O(Pt)                                                   0.000   -44.100
END